Mixtures having a flash-point below 23 C and containing more than 55 % nitrocellulose, whatever its nitrogen content or containing not more than 55 % nitrocellulose with a nitrogen content above 12.6 % (by dry mass), are substances of Class 1 (see UN Nos. 0340 or 0342) or of Class 4.1 (UN Nos. 2555, 2556 or 2557).